Positives Attract

Researchers find a new kind of hydrogen bond.

By Shannon Palus
Oct 29, 2015 5:00 AMNov 12, 2019 6:49 AM
Alison Mackey/Discover


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The saying “opposites attract” certainly applies to hydrogen bonds, which are made of one negatively and one positively charged atom. But chemists at the University of Copenhagen have discovered a new kind of hydrogen bond that, at first glance, should be impossible: It’s composed of two positively charged atoms, one phosphorus and one hydrogen.

Hydrogen bonds hold together pairs of molecules in water and DNA, and they help antibodies function. Typically, and logically, a positively charged hydrogen atom bonds to a negatively charged atom of oxygen, nitrogen or fluorine.

But phosphorus is slightly positive. Relying on a technique called infrared spectroscopy to explore the bonds between atoms, the researchers noticed it attaching to positive hydrogen atoms.

In a way, the new bond still follows the old adage. Charge isn’t always distributed evenly around an atom. And in this case, the scientists found that the phosphorus had a little patch of negative charge, just enough to hook up with the hydrogen atom.

For now, the new bond has only been seen in a lab. But it could play a role in helping scientists understand how proteins fold, a process that’s crucial to the most basic structure and function of living organisms.

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